Spectrometric identification of organic compounds :An Indian Adaptation

First published over 40 years ago Spectrometric Identification of Organic Compounds was the first text on the identification of organic compounds using spectroscopy. This text is now considered to be a classic. The key strength of this text is the extensive set of real-data problems (in Chapters 7 and 8). Even professional chemists use these spectra as reference data. Spectrometric Identification of Organic Compounds is written by and for organic chemists, and emphasizes the synergistic effect resulting from the interplay of the spectra. This book is characterized by its problem-solving approach with extensive reference charts and tables.

Table of Contents :

Chapter 1. Mass Spectrometry.

1.1 Introduction.

1.2 Instrumentation.

1.3 Ionization Methods.

1.4 Mass Analyzers.

1.5 Interpretation of El Mass Spectra.

1.6 Mass Spectra of Some Chemical Classes.

Chapter 2. Infrared Spectrometry.

2.1 Introduction.

2.2 Theory.

2.3 Instrumentation.

2.4 Sample Handling.

2.5 Interpretations of Spectra.

2.6 Characteristic Group Absorption of Organic Molecules.

Chapter 3. Proton Magnetic Resonance Spectrometry.

3.1 Introduction.

3.2 Theory.

3.3 Instrumentation and Sample Handling.

3.4 Chemical Shift.

3.5 Spin Coupling, Multiplets, Spin Systems.

3.6 Protons on Oxygen, Nitrogen, and Sulfur Atoms. Exchangeable Protons.

3.7 Coupling of Protons to Other Important Nuclei (19F, E, 31P, 29Si, and 13C.

3.8 Chemical Shift Equivalence.

3.9 Magnetic Equivalence (Spin-Coupling Equivalence).

3.10 AMX, ABX, and ABC Rigid Systems with Three Coupling Constants.

3.11 Confirmationally Mobile, Open-Chain Systems. Virtual Coupling.

3.12 Chirality.

3.13 Vicinal and Geminal Coupling.

3.14 Low-Range Coupling.

3.15 Selective Spin Decoupling. Double Resonance.

3.16 Nuclear Overhauser Effect, Difference Spectrometry, 1H 1H Proximity Through Space.

Chapter 4. Carbon-13 NMR Spectrometry.

4.1 Introduction.

4.2 Theory.

4.3 Interpretation of a Simple 13C Spectrum: Diethyl Phthalate.

4.4 Quantitative 13C Analysis.

4.5 Chemical Shift Equivalence.

4.6 DEPT.

4.7 Chemical Classes and Chemical Shifts.

Chapter 5. Correlation NMR Spectrometry; 2-D NMR.

5.1 Introduction.

5.2 Theory.

5.3 Correlation Spectrometry.

5.4 Ipsenol: 1H-1H COSY.

5.5 Caryophyllene Oxide.

5.6 13C-13C Correlations: Inadequate.

5.7 Lactose.

5.8 Relayed Coherence Transfer: TOCSY.

5.9 HMQC – TOCSY.

5.10 Roesy

5.11 Vgse

5.12 Gradient Field NMR.

Chapter 6. NMR Spectrometry of Other Important Spin 1/2 Nuclei.

6.1 Introduction.

6.2 15N Nuclear Magnetic Resonance.

6.3 19F Nuclear Magnetic Resonance.

6.4 29Si Nuclear Magnetic Resonance.

6.5 31P Nuclear Magnetic Resonance.

6.6 Conclusion.

Chapter 7. Solved Problems.

7.1 Introduction.

Chapter 8. Assigned Problems.

8.1 Introduction.

The Indian Adaptation of Spectrometric Identification of Organic Compounds, eighth edition of the book is reorganized, enhanced, and updated to offer complete coverage of Indian curriculum. Almost all spectroscopic techniques include updates in theory, instrumentation, and characterization of group absorptions UV-Visible Spectroscopy is now included as a part of the book. Chapter on Two-Dimensional NMR Spectroscopy is reorganized to explain 2D NMR techniques first with examples of simple molecules and then applied to analyze more complex molecules.

English